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中国海溶解氧化亚氮和甲烷浓度与海气通量分布特征及其影响机制

Characterization of the distribution of dissolved nitrous oxide and methane concentrations and air-sea fluxes in China Sea and their impact mechanisms

  • 摘要: 氧化亚氮(N2O)和甲烷(CH4)是重要的温室气体,其温室效应会对全球气候产生影响,然而目前关于中国海溶解N2O和CH4的研究较为分散,缺乏系统研究和整理。本研究梳理了近30年来中国海(渤海、黄海、东海和南海)中溶解N2O和CH4的浓度及分布特征和海-气交换通量,总结了中国海溶解N2O和CH4的时空分布特征,发现中国海表层N2O和CH4浓度的空间分布总体呈现从北至南逐步下降的特征,并与温度分布呈负相关关系。中国海N2O的年排放量约占全球海洋N2O年排放量的8.6%~9.8%;中国海CH4的年排放量约占全球海洋CH4年排放量的2.5%~2.6%。通过归纳影响N2O和CH4产生和释放的因素,发现陆源输入和沉积物-水界面交换是水体N2O和CH4的重要来源。通过分析N2O和CH4研究现状,发现目前中国海溶解N2O和CH4的研究缺乏连续性及系统性,对于产生和消耗机制等方面认识还不足。下一步,建议规范观测方法,加强高精度连续数据的获取,结合卫星遥感等大数据,运用同位素和生物化学结合的手段,更加准确地评估中国海N2O和CH4释放量,为评估中国海非二氧化碳温室气体潜在温室效应提供科学依据。

     

    Abstract: Nitrous oxide (N2O) and methane (CH4) are important greenhouse gases, and their greenhouse effects affect the global climate. However, the current researches on dissolved N2O and CH4 in China Sea are limited and lack of systematic researches and organizations. In this paper, the concentration distribution characteristics of dissolved N2O and CH4 in Bohai Sea, the Yellow Sea, East China Sea, the South China Sea and the sea-air exchange fluxes in the past 30 years are summarized and it is found that the spatial distribution of N2O and CH4 concentrations in the surface layer of China Sea generally shows a gradual decrease from the north to the south, and is negatively correlated with the rising temperature. The annual emission of N2O in China Sea accounts for about 8.6%−9.8% of the global oceanic N2O emission. The annual emission of CH4 accounts for about 2.5%−2.6% of the global oceanic CH4 emission. The factors affecting the production and release of N2O and CH4 show that land source input and sediment-water interface exchange are important sources in the water column. It is recommended to standardize the observation methods, strengthen the acquisition of high-precision continuous data, and combine big data such as satellite remote sensing with isotope and biochemical techniques to more precisely assess the emissions of N2O and CH4 in China Sea, thereby providing a scientific foundation for evaluating the potential greenhouse effects of non-carbon dioxide greenhouse gases in the China Sea.

     

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